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From The Collaborative International Dictionary of English v.0.48:
Overglaze \O"ver*glaze`\, a. (Ceramics) (a) Applied over the glaze; -- said of enamel paintings, which sometimes are seen to project from the surface of the ware. (b) Suitable for applying upon the glaze; -- said of vitrifiable colors used in ceramic decoration. [Webster 1913 Suppl.]