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From The Collaborative International Dictionary of English v.0.48:
Unware \Un*ware"\, a. [AS. unw[ae]r unwary. See Un- not, and Wary.] [1913 Webster] 1. Unaware; not foreseeing; being off one's guard. [Obs.] --Chaucer. --Fairfax. [1913 Webster] 2. Happening unexpectedly; unforeseen. [Obs.] [1913 Webster] The unware woe of harm that cometh behind. --Chaucer. [1913 Webster] -- Un*ware"ly, adv. [Obs.] -- Un*ware"ness, n. [Obs.] [1913 Webster]