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chieftain
From The Collaborative International Dictionary of English v.0.48:
Chieftain \Chief"tain\, n. [OE. cheftayn, chevetayn, OF. chevetain, F. capitaine, LL. capitanus, fr. L. caput head. Cf. Captain, and see chief.] A captain, leader, or commander; a chief; the head of a troop, army, or clan. Syn: Chief; commander; leader; head. See Chief. [1913 Webster] Chieftaincy

